Synthesis of symmetrical chromeno[2,3-b]chromenes on the basis of о-quinone methides and 1,1-bis(morpholino)ethene

[Figure not available: see fulltext.] The reaction of 1,1-bis(morpholino)ethene with precursors of о-quinone methides derived from Mannich bases of phenols and 2-naphthols provided a series of chromeno[2,3-b]chromenes. The cascade process included a hetero-Diels–Alder reaction between о-quinone methide and ketenaminal, elimination of secondary amine, and [4+2] cycloaddition between о-quinone methide and the chromene intermediate. © 2018, Springer Science+Business Media, LLC, part of Springer Nature.

Authors
Osyanin V.A. 1, 2 , Osipov D.V.1 , Demidov M.R.1 , Krasnikov P.E.1 , Klimochkin Y.N.1
Publisher
Латвийский институт органического синтеза Латвийской академии наук / Springer New York Consultants Bureau
Number of issue
12
Language
English
Pages
1310-1314
Status
Published
Volume
53
Year
2017
Organizations
  • 1 Samara State Technical University, 244 Molodogvardeiskaya St., Samara, 443100, Russian Federation
  • 2 RUDN University, 6 Miklukho-Maklaya St., Moscow, 117198, Russian Federation
Keywords
cascade reactions; chromeno[2,3-b]chromenes; Diels–Alder reaction; ketenaminals; о-quinone methides
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/5131/
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