Oxidative Dehomologation of Aldehydes with Oxygen as a Terminal Oxidant

A mild, efficient protocol for oxidative cleavage of C-C bonds in aldehydes has been developed that employs alkali metal hydrides as reagents and oxygen from air as a terminal oxidant. The method is applicable to a broad substrate range. © 2017 American Chemical Society.

Authors
Shipilovskikh S.A.1 , Rubtsov A.E.1 , Malkov A.V. 2, 3
Journal
Organic Letters
Number of issue
24
Language
English
Pages
6760-6762
Status
Published
Link
External link
DOI
10.1021/acs.orglett.7b03512
Volume
19
Year
2017
Organizations
  • 1 Department of Chemistry, Perm State University, Bukireva 15, Perm, 614990, Russian Federation
  • 2 Department of Chemistry, Loughborough University, Loughborough, Leics, LE11 3TU, United Kingdom
  • 3 Department of Organic Chemistry, RUDN University, 6 Miklukho-Maklaya Street, Moscow, 117198, Russian Federation
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/5107/
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