Synthesis, spectral and crystallographic studies of coordination compounds of some d and f metals with N-nitrozo-N-(methyl)ethylhydroxylamine

Eleven complexes of some d and f metals with N-nitrozo-N- methylhydroxylamine (NMHA) and N-nitrozo-N-ethylhydroxylamine (NEHA) were synthesized, separated out in a crystalline state, and characterized by a set of physicochemical methods (elemental analysis, X-ray diffraction, IR and UV spectroscopy). The crystal and molecular structure of Cu(NEHA)2 was solved using X-ray diffraction. The composition and stability constants of the complexes in solutions were determined spectrophotometrically. The organic ligands were shown to be coordinated to the metal cation in the bidentate chelate mode in the anionic form. © 2014 Pleiades Publishing, Ltd.

Authors
Editors
-
Publisher
IAPC Nauka/Interperiodica
Number of issue
3
Language
English
Pages
192-195
Status
Published
Department
-
Number
-
Volume
59
Year
2014
Organizations
  • 1 People's Friendship University of Russia, ul. Miklukho-Maklaya 6, Moscow 117198, Russian Federation
  • 2 Karpov Institute of Physical Chemistry, ul. Vorontsovo pole 10, Moscow 103064, Russian Federation
  • 3 Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast 142432, Russian Federation
Keywords
Crystal structure; Crystalline materials; Synthesis (chemical); Ultraviolet spectroscopy; X ray diffraction; Bidentate chelates; Coordination compounds; Crystal and molecular structure; Crystalline state; Crystallographic studies; Organic ligands; Physicochemical methods; Stability constants; Coordination reactions
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/4992/