Diaquabis[N-(2-fluorobenzyl)-N-nitrosohydroxylaminato-κ2 O,O′]nickel(II)

In the centrosymmetric title compound, [Ni(C7H 6FN2O2)2-(H2O) 2], the NiII cation is in a slightly distorted octahedral environment and is surrounded by four O atoms from the N - O groups of the organic ligands [Ni - O = 2.0179 (13) and 2.0283 (12) Å], and two water molecules [Ni - O = 2.0967 (14) Å]. The N-(2-fluorobenzyl)-N- nitrosohydroxylaminate monoanions act as bidentate chelating ligands. In the crystal, the Ni cations in the columns are shifted in such a way that the coordinated water molecules are involved in the formation of hydrogen bonds with the O atoms of the organic species of neighbouring molecules. Thus, a two-dimensional network parallel to (100) is built up by hydrogen-bonded molecules.

Authors
Editors
-
Publisher
-
Number of issue
3
Language
English
Pages
m98-m99
Status
Published
Department
-
Number
-
Volume
70
Year
2014
Organizations
  • 1 Peoples' Friendship University of Russia, 6 Miklukho-Mallaya, 117198 Moscow, Russian Federation
  • 2 Karpov Institute of Physical Chemistry, 10 Vorontsovo Pole, 105064 Moscow, Russian Federation
  • 3 Institute of Problems of Chemical Physics (IPCP), Russian Academy of Sciences (RAS), Academician Semenov Avenue 1, Chernogolovka, Moscow Region, 142432, Russian Federation
Keywords
Data-to-parameter ratio = 11.9; Mean σ(C-C) = 0.003 Å; R factor = 0.022; Single-crystal X-ray study; T = 293 K; wR factor = 0.066
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/4851/