Mesoporous Hierarchically Hollow Flower-Like CoAl-LDH@N,S-doped Graphene@Pd Nanoarchitectures for Heck Couplings

Abstract: A smart strategy for the synthesis of hierarchical CoAl-LDH hollow spheres assembled with nitrogen and sulfur co-doped graphene for high holding of palladium nanoparticles (CoAl-LDH@N,S-G@Pd) is reported. This architecture exhibited excellent activity in Heck reactions with TOF as high as 1633 h−1 due to a strong metal–support interaction, good electron transfers and high surface area. Graphic Abstract: [Figure not available: see fulltext.]. © 2019, Springer Science+Business Media, LLC, part of Springer Nature.

Authors
Rohani S.1 , Mohammadi Ziarani G. , Badiei A.2 , Ziarati A.2 , Luque R. 3, 4
Publisher
Baltzer Science Publishers, Baarn/Kluwer Academic Publishers
Language
English
Status
Published
Year
2019
Organizations
  • 1 Department of Chemistry, Faculty of Science, University of Alzahra, Tehran, Iran
  • 2 School of Chemistry, College of Science, University of Tehran, Tehran, Iran
  • 3 Departamento de Quimica Organica, Universidad de Cordoba, Campus de Rabanales, Edificio Marie Curie, Córdoba, 14014, Spain
  • 4 Peoples Friendship University of Russia (RUDN University), 6 Miklukho Maklaya str, Moscow, 117198, Russian Federation
Keywords
Heck coupling; Heterogeneous catalysis; Layered double hydroxide; N, S doped graphene; Nanostructure
Date of creation
19.07.2019
Date of change
19.07.2019
Short link
https://repository.rudn.ru/en/records/article/record/38834/
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