Synthesis and Structure of the Iron(III) Chloride Complex with 1-Morpholino-3,3-dimethyl-3,4-dihydroisoquinoline

The iron(III) chloride complex with 1-morpholino-3,3-dimethyl-3,4-dihydroisoquinoline (I) was synthesized and characterized by X-ray crystallography and IR and electronic spectroscopy. Structure I is built of centrosymmetric binuclear [(FeCl3)2(μ-O)]2- anions and (HL)+ cations. The coordination of the Fe3+ atom is tetrahedral. The bond lengths are Fe-O(br) 1.748 Å, average Fe-Cl 2.221 Å. The (HL)+ cation is protonated at the nitrogen atom of the dihydroisoquinoline moiety.

Authors
Sokol V.I.1 , Ryabov M.A. 2 , Merkur'eva N.Yu. 2 , Sergienko V.S.1 , Davydov V.V. 2 , Shklyaev Yu.V.3
Publisher
IAPC Nauka/Interperiodica
Number of issue
8
Language
English
Pages
1199-1203
Status
Published
Volume
46
Year
2001
Organizations
  • 1 Kurnakov Inst. Gen. and Inorg. Chem., Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117907, Russian Federation
  • 2 Russ. Univ. of Peoples' Friendship, ul. Miklukho-Maklaya 6, Moscow, 117198, Russian Federation
  • 3 Institute of Technical Chemistry, Ural Division, Russian Academy of Sciences, ul. Lenina 13, Perm, 614600, Russian Federation
Date of creation
19.10.2018
Date of change
13.04.2021
Short link
https://repository.rudn.ru/en/records/article/record/379/