Interaction of a trinuclear copper(i) pyrazolate with alkynes and carbon-carbon triple bond activation

The trinuclear copper(i) pyrazolate {[3,5-(CF3)2Pz]Cu}3 forms η2-copper/alkyne triple bond coordinated structures in the presence of acetylenes. There is no coordination of copper atoms to the phenyl ring of phenylacetylene and copper(i) acetylide formation during the interaction. It was observed that the complexes formed are the active catalytic species in click reactions. © The Royal Society of Chemistry.

Authors
Titov A.A. 1 , Larionov V.A. 1, 2 , Smol'yakov A.F. 1 , Godovikova M.I.1 , Titova E.M. 1, 2 , Maleev V.I. 1 , Shubina E.S. 1
Journal
Chemical Communications
Publisher
Royal Society of Chemistry
Number of issue
3
Language
English
Pages
290-293
Status
Published
Link
External link
DOI
10.1039/c8cc08592g
Volume
55
Year
2019
Organizations
  • 1 A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences (INEOS RAS), Vavilov St. 28, Moscow, 119991, Russian Federation
  • 2 Peoples' Friendship University of Russia (RUDN University), Miklukho-Maklaya St. 6, Moscow, 117198, Russian Federation
Date of creation
04.02.2019
Date of change
04.02.2019
Short link
https://repository.rudn.ru/en/records/article/record/36114/
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