Electronic absorption spectra and the structure of the ligand in metal complexes with purpurin

Purpurin complexes with metals are formed due to metal coordination at the peri- or ortho-hydroxycarbonyl group involving anthraquinoid tautomers. The πl,π*bands of metal purpurinates correspond to 1,10- and 1,4-anthraquinoid anions, 9,10-anthraquinoid structures are not typical of them. © 2005 Pleiades Publishing, Inc.

Authors
Fain V.Ya. 1 , Zaitsev B.E. 1 , Ryabov M.A. 1
Journal
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Number of issue
3
Language
English
Pages
221-224
Status
Published
Link
External link
DOI
10.1007/s11173-005-0080-8
Volume
31
Year
2005
Organizations
  • 1 Peoples Friendship University, ul. Miklukho-Maklaya 6, Moscow, 117198, Russian Federation
Keywords
Absorption; Absorption spectroscopy; Coordination reactions; Derivatives; Ionization; Molecular structure; Spectrophotometry; Anthaquinoid forms; Electronic absorption spectra; Metal complexes; Tautomeric; Complexation
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/3509/
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