Proceedings of ASMTA 2006: 13th International Conference on Analytical and Stochastic Modelling Techniques and Applications.
2006.
P. 117-123
Slow hindered rotation of CF3 group in radical anion of ortho nitrobenzotrifluoride in N,N′-dimethylformamide and reconstruction of EPR spectrum
The temperature dependence of the EPR spectrum of the 2-CF3-C6H4-NO*2 radical anion in anhydrous N,N′-dimethylformamide, caused by hindered internal rotation of the CF3 group with an extreme activation energy of 34700 J·mol-1, was experimentally studied and reconstructed. © 2007 by Allerton Press, Inc.
Authors
Polenov E.A.1
,
Shundrin L.A.2
,
Melnikov P.V.1
,
Bozhenko K.V.
3
Number of issue
8
Language
English
Pages
1268-1273
Status
Published
Volume
70
Year
2006
Organizations
- 1 Lomonosov State Academy of Fine Chemical Technology, Moscow 117571, Russian Federation
- 2 Novosibirsk Institute for Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk 630090, Russian Federation
- 3 Peoples Friendship University of Russia, Moscow 117198, Russian Federation
Keywords
Activation energy; Fluorine compounds; Negative ions; Paramagnetic resonance; Temperature; Internal rotation; Nitrobenzotrifluoride; Radical anion; Nitrobenzene
Date of creation
19.10.2018
Date of change
19.10.2018
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