Synthesis of benzoazocines from substituted tetrahydroisoquinolines and activated alkynes in a tetrahydropyridine ring expansion

Tetrahydroisoquinolines underwent tandem piperidine ring enlargement in the presence of activated alkynes in acetonitrile or methanol, producing tetrahydrobenzo[d]azocines in high yields. © Wiley-VCH Verlag GmbH & Co. KGaA, 2007.

Authors
Voskressensky L.G. 1 , Listratova A.V. 1 , Borisova T.N. 1 , Alexandrov G.G. 1 , Varlamov A.V. 1
Journal
European Journal of Organic Chemistry
Number of issue
36
Language
English
Pages
6106-6117
Status
Published
Link
External link
DOI
10.1002/ejoc.200700602
Year
2007
Organizations
  • 1 Organic Chemistry Department, Russian Peoples Friendship University, 6, Miklukho-Maklaya St., Moscow 117198, Russian Federation
Keywords
Activated alkynes; Azocine; Ring expansion; Tandem transformation; Tetrahydroisoquinolines
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/3164/
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