Syntheses, structures, and geometric and spectral characteristics of the hexachlorodicuprate(II) complexes with the protonated 4-azafluoren-9-one derivatives: The crystal and molecular structures of bis(4-azafluoren-9-onium) hexachlorodiaquadicuprate(II) dihydrate

Three complexes containing hexachlorodicuprate(II) anions and protonated 4-azafluorenone derivatives as counterions were isolated. The crystal and molecular structures of 4-azafluoren-9-one, (HL1) 2[(CuCl2(H2O))2(μ-Cl) 2] • 2H2O (L1), and spectral characteristics of the complexes were determined. Relationships relating the degree of distortion of the crystal structure of the hexachlorodicuprate(II) anions to the spectral characteristics of the compounds were proposed on the basis of the experimental and published data. © 2009 Pleiades Publishing, Ltd.

Editors
-
Publisher
-
Number of issue
1
Language
English
Pages
6-11
Status
Published
Department
-
Number
-
Volume
35
Year
2009
Organizations
  • 1 Peoples Friendship University, ul. Miklukho-Maklaya 6, Moscow, Russian Federation
  • 2 Karpov Research Institute of Physical Chemistry, ul. Vorontsovo pole 10, Moscow 103064, Russian Federation
Keywords
Copper compounds; Molecular structure; Negative ions; Counter-ions; Crystal and molecular structures; Degree of distortions; Dihydrate; Protonated; Spectral characteristics; Crystal structure
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/3007/