Tetrabutoxytitanium adduct formation in esterification reactions

Different mechanisms of the catalytic action of tetrabutoxytitanium in esterification and transesterification reactions are analyzed. New evidence is obtained in favor of the nonionic mechanism of ester formation catalysis by glycol-tetrabutoxytitanium adducts in esterification reactions. © 2009 Pleiades Publishing, Ltd.

Authors
Evtushenko Yu.M. 1 , Krushevskii G.A. 1, 2, 3 , Miroshnikov Yu.P. 1, 2, 3 , Zaitsev B.E. 1, 2, 3 , Dibua Kat Konstant O.
Journal
Theoretical Foundations of Chemical Engineering
Number of issue
5
Language
English
Pages
771-778
Status
Published
Link
External link
DOI
10.1134/S0040579509050285
Volume
43
Year
2009
Organizations
  • 1 ZAO Elektroizolit, Zavodskaya ul. 1, Khot'kovo, Moscow Oblast 141371, Russian Federation
  • 2 Moscow State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow 119571, Russian Federation
  • 3 Peoples Friendship University of Russia, ul. Miklukho-Maklaya 6, Moscow 117198, Russian Federation
Keywords
Adduct formation; Different mechanisms; Ester formation; Esterification reactions; Nonionic; Transesterification reaction; Esters; Glycols; Esterification
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/2917/
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Article
Voskressensky L.G., Borisova T.N., Sorokina E.A., Kulikova L.N., Kleimenov A.V., Tolkunov S.V., Varlamov A.V.
Chemistry of Heterocyclic Compounds. Латвийский институт органического синтеза Латвийской академии наук / Springer New York Consultants Bureau. Vol. 45. 2009. P. 1248-1251