Synthesis and spectroscopic study of iron(III) and copper(II) chloride complexes with 2-(3,3-dimethyl-1,2,3,4-tetrahydroisoquinolylidene-1)-5,5- dimethyl-2,3,5,6-tetrahydroimidazo[2,1-a]isoquinoline-3-one (L). The crystal structure of L

Complexes of Fe(III) and Cu(II) chlorides with 2-(3,3,-dimethyl-1,2,3,4- tetrahydroisoquinolylidene-1)-5,5-dimethyl-2,3,5,6-tetrahydroimidazo[2,1-a] isoquinoline-3-one (L) were synthesized and studied by IR and electronic absorption spectroscopy. X-ray diffraction analysis of compound L was carried out. The molecule of L was found to crystallize in the form of cis-isomer with the proton localized on the nitrogen atom of the dihydroisoquinoline fragment.

Authors
Sokol V.I.1 , Davydov V.V. 2 , Merkur'eva N.Yu. 2 , Ryabov M.A. 2 , Sergienko V.S.1 , Pervushina S.A. 2 , Shklyaev Yu.V.3
Editors
-
Publisher
-
Number of issue
11
Language
English
Pages
810-817
Status
Published
Department
-
Number
-
Volume
29
Year
2003
Organizations
  • 1 Kurnakov Inst. Gen. and Inorg. Chem., Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russian Federation
  • 2 University of Peoples' Friendship, ul. Miklukho-Maklaya 6, Moscow, 117198, Russian Federation
  • 3 Institute of Technical Chemistry, Ural Division, Russian Academy of Sciences, Perm, Russian Federation
Keywords
2 (3,3 dimethyl 1,2,3,4 tetrahydroisoquinolylidene 1) 5,5 dimethyl 2,3,5,6 tetrahydroimidazo[2,1 a]isoquinolin 3 one; chlorine; copper complex; iron complex; isoquinoline derivative; nitrogen; proton; unclassified drug; absorption spectroscopy; article; atomic particle; chemical analysis; chemical binding; chemical structure; cis isomer; complex formation; crystal structure; crystallization; physical chemistry; spectroscopy; structure analysis; X ray diffraction
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/29/