8H-Chromeno[2',3':4,5]imidazo[2,1-a]isoquinoline

The title compound, C18H12N2O, comprises two aromatic fragments, viz., imidazo[2,1-a]isoquinoline and benzene, linked by oxygen and methyl-ene bridges. Despite the absence of a common conjugative system within the mol-ecule, it adopts an essentially planar conformation with an r.m.s. deviation of 0. 036 Å. In the crystal, due to this structure, mol-ecules form stacks along the b axis by π⋯π stacking inter-actions, with shortest C⋯C distances in the range 3.340 (4)-3.510 (4) Å. The mol-ecules are bound by inter-molecular C - H⋯O inter-actions within the stacks and C - H⋯π inter-actions between the stacks.

Authors
Safarov S.1 , Voskressensky L.G. 2 , Bizhko O.V. 2 , Kulikova L.N. 2 , Khrustalev V.N.3
Number of issue
3
Language
English
Status
Published
Volume
66
Year
2010
Organizations
  • 1 V. I. Nikitin Institute of Chemistry, Ayni St. 299/2, Dushanbe 734063, Tajikistan
  • 2 Organic Chemistry Department, Russian Peoples Friendship University, Miklukho-Maklai St 6, Moscow 117198, Russian Federation
  • 3 A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov St 28, B-334, Moscow 119991, Russian Federation
Keywords
Data-to-parameter ratio = 14.4; Mean σ(C-C) = 0.004 Å; R factor = 0.066; Single-crystal X-ray study; T = 100 K; WR factor = 0.182
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/2794/
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