(4R*,4aR*,7aS*)-5-Oxo-6-phenyl-4a,5,6,7,7a, 8-hexahydro-4H-furo[2,3-f]isoindole-4-carboxylic acid

The asymmetric unit of the title compound, C17H 15NO4, contains two independent molecules with similar geometric parameters. In both molecules, the conformation of the cyclohexene ring is half-chair, while the pyrrolidinone ring adopts an envelope conformation with the γ-carbon atom of the -pyrrolidinone ring as the flap. In the crystal, O - H⋯O hydrogen bonds between the carboxylic and carbonyl groups link alternate independent molecules into chains propagating in the b-axis direction. The crystal packing also features weak C - H⋯π interactions.

Authors
Horak Y.I.1 , Lytvyn R.Z.1 , Zubkov F.I. 2 , Nikitina E.V. 2 , Homza Y.V.1 , Lis T.3 , Kinzhybalo V.4 , Obushak M.D.1
Number of issue
2
Language
English
Pages
o273-o274
Status
Published
Volume
69
Year
2013
Organizations
  • 1 Department of Organic Chemistry, Ivan Franko National University of Lviv, Kyryla and Mefodiya 6, Lviv 79005, Ukraine
  • 2 Department of Organic Chemistry, Peoples' Friendship University of Russia, 6 Miklukho-Maklaya St., Moscow 117198, Russian Federation
  • 3 Faculty of Chemistry, University of Wrocław, 14 Joliot-Curie St, 50-383 Wrocław, Poland
  • 4 Institute of Low Temperature and Structure Research, Okolna 2, 50-422 Wrocław, Poland
Keywords
data-to-parameter ratio = 32.9; mean σ(C-C) = 0.001 Å; R factor = 0.044; single-crystal X-ray study; T = 120 K; wR factor = 0.127
Date of creation
19.10.2018
Date of change
13.08.2021
Short link
https://repository.rudn.ru/en/records/article/record/2129/
Share

Other records