Synthesis of pyrrolo[1,2-a][1,6]benzodiazonines from pyrrolo[1,2-a][1,4] benzodiazepines and alkynes containing electron-acceptor substituents

It has been established that the reaction of pyrrolo[1,2-a][1,4] benzodiazepines with activated alkynes gives pyrrolo[1,2-a][1,6]benzodiazonines as the products of diazepine ring expansion. In the case of pyrrolo[1,2-a][1,4] benzodiazepine, substituted with formyl group at the pyrrole ring, both expansion and cleavage of the diazepine fragment can occur. © 2013 Springer Science+Business Media New York.

Authors
Voskressensky L.G. 1 , Borisova T.N. 1 , Babakhanova M.I. 1 , Chervyakova T.M. 1 , Titov A.A. 1 , Butin A.V.2, 3 , Nevolina T.A.2, 3 , Khrustalev V.N.4 , Varlamov A.V. 1
Publisher
Латвийский институт органического синтеза Латвийской академии наук / Springer New York Consultants Bureau
Number of issue
7
Language
English
Pages
1024-1032
Status
Published
Volume
49
Year
2013
Organizations
  • 1 Peoples' Friendship University of Russia, 6 Miklukho-Maklaya St., Moscow 117198, Russian Federation
  • 2 Research Institute for Heterocyclic Compounds, Kuban State University of Technology, 2 Moscow St., Krasnodar 350072, Russian Federation
  • 3 Perm State National Research University, 15 Bukirev St., Perm 614990, Russian Federation
  • 4 A. N. Nesmeyanov Institute of Organoelemental Compounds, Russian Academy of Sciences, 28 Vavilov St., Moscow 119991, Russian Federation
Keywords
activated alkynes; diazepine ring expansion; diazepine ring opening; pyrrolo[1,2-a][1,4]benzodiazepines; pyrrolo[1,2-a][1,6]benzodiazonines
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/1986/
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