Synthesis and three-dimensional structures of substituted 4-silyl-4-piperidols

1,2 5-Trimethyl-4-(methyldiphenylsilyl)- and 4-(dimethylphenyl)silyl-4-piperidols were obtained. The isomers of these piperidols of the γ series, which exist in the chair conformation, have all of their substituents, except the hydroxyl group, equatorially oriented. The isomers of the α series exist in solution in the form of an equilibrium mixture of chair and boat conformations, and all of the substituents, except the silyl grouping, are equatorially oriented in the chair conformation. © 1977 Plenum Publishing Corporation.

Authors
Prostakov N.S. 1 , Varlamov A.V. 1 , Zvolinskii V.P. 1 , Cherenkova G.I.1 , Butros B.M.1 , Sintra M.E.1
Publisher
Латвийский институт органического синтеза Латвийской академии наук / Springer New York Consultants Bureau
Number of issue
4
Language
English
Pages
421-424
Status
Published
Volume
12
Year
1977
Organizations
  • 1 Patrice Lumumba International-Friendship University, Moscow, Russian Federation
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/1697/
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Prostakov N.S., Gaivoronskaya L.A., Mokhomon K.M.S., Zvolinskii V.P., Savina A.A., Makhsida M., Karrasko V.H.O.
Chemistry of Heterocyclic Compounds. Латвийский институт органического синтеза Латвийской академии наук / Springer New York Consultants Bureau. Vol. 12. 1977. P. 424-428