Crystal structure and Hirshfeld surface analysis of (Z)-4-({[2-(benzo[b]thiophen-3-yl)cyclopent-1-en-1-yl]methyl}(phenyl)amino)-4-oxobut-2-enoic acid

In the title compound, C24H21NO3S, the cyclopentene ring adopts an envelope conformation. In the crystal, molecules are linked by C-H⋯π interactions, forming ribbons along the a axis. Intermolecular C-H⋯O hydrogen bonds connect these ribbons to each other, forming layers parallel to the (0 1) plane. The molecular packing is strengthened by van der Waals interactions between the layers. The intermolecular contacts were quantified using Hirshfeld surface analysis and two-dimensional fingerprint plots, revealing the relative contributions of the contacts to the crystal packing to be H⋯H 46.0%, C⋯H/H⋯C 21.1%, O⋯H/H⋯O 20.6% and S⋯H/H⋯S 9.0%. © 2024 International Union of Crystallography. All rights reserved.

Authors
Yakovleva E.D. , Shelukho E.R. , Grigoriev M.S. , Hasanov K.I. , Sadikhova N.D. , Akkurt M. , Bhattarai A.
Publisher
International Union of Crystallography
Issue number
Pt 5
Language
English
Pages
537-542
State
Published
Volume
80
Year
2024
Organizations
  • 1 RUDN University, 6 Miklukho-Maklaya St., Moscow, 117198, Russian Federation
  • 2 Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskiy prospect 31-4, Moscow, 119071, Russian Federation
  • 3 Western Caspian University, Istiqlaliyyat Street 31, Baku, AZ 1001, Azerbaijan
  • 4 Azerbaijan Medical University, Scientific Research Centre (SRC), A. Kasumzade St. 14, Baku, AZ 1022, Azerbaijan
  • 5 Department of Chemistry, Baku State University, Z. Xalilov Str. 23, AZ, Baku, 1148, Azerbaijan
  • 6 Department of Physics, Faculty of Sciences, Erciyes University, Kayseri, 38039, Turkey
  • 7 Department of Chemistry, M.M.A.M.C. (Tribhuvan University), Biratnagar, Nepal
Keywords
acylation; crystal structure; Hirshfeld surface analysis; maleic acid amide; thienylallylamine; weak interaction
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