Bright luminescence of new low-melting copper(<scp>i</scp>) chlorides with compact organic cations

In this paper, we comprehensively studied two ACl/CuCl systems with dimethylammonium (DMA<jats:sup>+</jats:sup>) and acetamidinium (Ac<jats:sup>+</jats:sup>) organic cations and proved the formation of five new crystalline phases: DMACu<jats:sub>2</jats:sub>Cl<jats:sub>3</jats:sub>, DMACuCl<jats:sub>2</jats:sub>, DMA<jats:sub>4</jats:sub>[Cu<jats:sub>2</jats:sub>Cl<jats:sub>6</jats:sub>], DMA<jats:sub>3</jats:sub>CuCl<jats:sub>4</jats:sub>, and AcCuCl<jats:sub>2</jats:sub>.

Authors
Belikova Daria E. 1 , Fateev Sergey A. 1 , Khrustalev Victor N. 2, 3 , Kozhevnikova Vladislava 4 , Ordinartsev Artem A. 1 , Dzuban Alexander V. 4 , Goodilin Eugene A. 1, 4 , Tarasov Alexey B. 1, 4
Journal
Journal of Materials Chemistry C
Publisher
Royal Society of Chemistry
Issue number
34
Language
English
Pages
13537-13544
State
Published
DOI
10.1039/D4TC02152E
Volume
12
Year
2024
Organizations
  • 1 Laboratory of New Materials for Solar Energetics, Faculty of Materials Science, Lomonosov Moscow State University, 119991 Moscow, Russian Federation
  • 2 Inorganic Chemistry Department, Peoples’ Friendship University of Russia (RUDN University), 117198 Moscow, Russian Federation
  • 3 Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prosp. 47, Moscow 119991, Russia
  • 4 Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russian Federation
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