Hydrogenation and halogenation of 6-phenyl-5-azabenzo[f]fluoranthene and reduction of its adducts with acrylonitrile

The hydrogenation of 6-phenyl-5-azabenzo[f]fluoranthene in the presence of rhenium heptasulfide takes place in the meso positions of its azaanthracene fragment. The reaction of 5-azabenzo[f]fluoranthene with acid chlorides and aluminum chloride in nitrobenzene gives its 8-chloro derivative. The reduction of the adducts of the diene synthesis of 6-phenyl-5-azabenzo[f]fluoranthene with acrylonitrile by means of sodium in butyl alcohol leads to the corresponding aminomethyl derivatives and a product of retrodiene synthesis, viz., the starting azabenzofluoranthene. The reduction of the adduct of the diene synthesis of 1,3-diphenyl-2-azaanthracene with acrylonitrile proceeds similarly. © 1982 Plenum Publishing Corporation.

Editors
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Publisher
Латвийский институт органического синтеза Латвийской академии наук / Springer New York Consultants Bureau
Number of issue
2
Language
English
Pages
182-184
Status
Published
Department
-
Number
-
Volume
18
Year
1982
Organizations
  • 1 Patrice Lumumba Peoples' Friendship University, Moscow, 117923, Russian Federation
Keywords
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Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/1465/