Copper(II) chloride complex with5,5-dimethyl-5,6-dihydrotetrazolo[5,1-a] isoquinoline

Copper(II) complex with 5,5-dimethyl-5,6-dihydrotetrazolo[5,1-a] isoquinoline [CuLCl2]n has been synthesized. X-ray crystallography showed that the complex has a polymeric chain structure. Ligand L is coordinated to the copper(II) atom through the nitrogen atom in position 1 of the tetrazole ring. The coordination polyhedron around the cooper(II) atom is a strongly distorted five-vertex polyhedron. One corner is occupied by the nitrogen atom of L, and the other four are occupied by bridging chlorine atoms.

Authors
Sokol V.I.1 , Davydov V.V. 2 , Merkur'Eva N.Yu. 2 , Ryabov M.A. 2 , Sergienko V.S.1 , Pervushina S.A. 2 , Shklyaev Yu.V.3
Publisher
IAPC Nauka/Interperiodica
Number of issue
6
Language
English
Pages
791-795
Status
Published
Volume
48
Year
2003
Organizations
  • 1 Kurnakov Inst. Gen. and Inorg. Chem., Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russian Federation
  • 2 Peoples' Friendship University, ul. Miklukho-Maklaya 6, Moscow, 117198, Russian Federation
  • 3 Institute of Technical Chemistry, Ural Division, Russian Academy of Sciences, ul. Lenina 13, Perm, 614600, Russian Federation
Keywords
5,5 dimethyl 5,6 dihydrotetrazolo[5,1 a]isoquinoline; copper chloride; isoquinoline derivative; nitrogen; unclassified drug; article; chemical structure; complex formation; synthesis; X ray crystallography
Date of creation
19.10.2018
Date of change
12.04.2021
Short link
https://repository.rudn.ru/en/records/article/record/116/