Synthesis and structure of iron(III) chloride complex with 3-(2-Furyl)-5,5-dimethyl-8,9-dimethoxy-5,6-dihydro-1,2,4-triazolo[3,4-a] isoquinoline

An iron (III) chloride complex with 3-(2-furyl)-5,5-dimethyl-8,9-dimethoxy- 5,6-dihydro-1,2,4-triazolo[3,4-a]isoquinoline (L) was synthesized. The crystal structure of (HL2)[FeCl4] (I) was determined by X-ray single-crystal diffraction. A specific structural feature of compound I is a singly charged cation in which two structurally independent organic molecules L are linked by an N(2)⋯H⋯N(2) hydrogen bond. The tetrahedral [FeCl4]- anion has the usual geometry. The Fe-Cl bond lengths are in the 2.163(2)-2.183(2) Å range.

Authors
Sokol V.I.1 , Davydov V.V. 2 , Merkur'eva N.Yu. 2 , Pervushina S.A. 2 , Ryabov M.A. 2 , Sergienko V.S.1 , Glushkov V.A.3 , Shklyaev Yu.V.3
Journal
Russian Journal of Inorganic Chemistry
Publisher
IAPC Nauka/Interperiodica
Number of issue
2
Language
English
Pages
217-223
Status
Published
Link
External link
Volume
48
Year
2003
Organizations
  • 1 Kurnakov Inst. Gen. and Inorg. Chem., Russian Academy of Sciences, Leninskiipr. 31, Moscow, 119991, Russian Federation
  • 2 Peoples' Friendship University, ul. Miklukho-Maklaya 6, Moscow, 117198, Russian Federation
  • 3 Institute of Technical Chemistry, Ural Division, Russian Academy of Sciences, ul Lenina 13, Perm, 614600, Russian Federation
Keywords
3 (2 furyl) 5,5 dimethyl 8,9 dimethoxy 5,6 dihydro 1,2,4 triazolo[3,4 a]isoquinoline; ferrous chloride; iron complex; isoquinoline derivative; unclassified drug; article; crystal structure; hydrogen bond; synthesis; X ray diffraction
Date of creation
19.10.2018
Date of change
09.04.2021
Short link
https://repository.rudn.ru/en/records/article/record/111/
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