A synthetic route to artificial chiral α-amino acids featuring a 3,4-dihydroisoquinolone core through a Rh(iii)-catalyzed functionalization of allyl groups in chiral Ni(ii) complexes

The first asymmetric synthetic route to artificial α-amino acids with a 3,4-dihydroisoquinolone skeleton was elaborated via a straightforward Rh(iii)-catalyzed C–H activation/annulation reaction.

Authors
Arsenov Mikhail A.1 , Stoletova Nadezhda V.1 , Smol'yakov Alexander F.1, 2 , Savel'yeva Tat'yana F.1 , Maleev Victor I.1 , Loginov Dmitry A.1, 2 , Larionov Vladimir A. 1, 3
Journal
Organic and Biomolecular Chemistry
Publisher
Royal Society of Chemistry
Number of issue
46
Language
English
Pages
9143-9149
Status
Published
DOI
10.1039/d3ob01513k
Volume
21
Year
2023
Organizations
  • 1 A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences (INEOS RAS), Vavilov Str. 28, bld. 1, 119334 Moscow, Russian Federation
  • 2 Plekhanov Russian University of Economics, Stremyanny Per. 36, 117997 Moscow, Russian Federation
  • 3 Peoples’ Friendship University of Russia (RUDN University), Miklukho-Maklaya Str. 6, 117198 Moscow, Russian Federation
Date of creation
29.02.2024
Date of change
29.02.2024
Short link
https://repository.rudn.ru/en/records/article/record/106321/
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