Oxidative reactions of azines. 1. Ketohydroxylation of 4-phenyl-1,2,5,6-tetrahydropyridines. Synthesis and structure of 3,4-dihydroxy-4-phenylpiperidin-2-ones and their acetoxy derivatives

N-Alkyl substituted 4-phenyl-1,2,5,6-tetrahydropyridines which do not undergo Wagner hydroxylation are converted in good yields to the corresponding 3,4-dihydroxy-2-oxo-pipendines under modified conditions for this reaction. The molecular structures of a 3,4-dihydroxy-4-phenyl-pipendin-2-one and its diacetatate have been studied by x-ray crystalographic analysis. ©1996 Plenum Publishing Corporation.

Авторы
Издательство
Латвийский институт органического синтеза Латвийской академии наук / Springer New York Consultants Bureau
Номер выпуска
2
Язык
Английский
Страницы
197-201
Статус
Опубликовано
Том
32
Год
1996
Организации
  • 1 Russian University of National Friendship, Moscow 117198, Russian Federation
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