Supramolecular organic frameworks derived from bromoaryl-substituted dichlorodiazabutadienes via Cl???Br halogen bonding

1-Aryl-3-(4-bromophenyl)-4,4-dichloro-1,2-diazabuta-1,3dienes were synthesized via copper-catalyzed reaction of 4-bromobenzaldehyde arylhydrazones with CCl4. X-ray diffraction analysis revealed non-covalent Cl???Br interactions in the crystalline state and formation of 3D supramolecular framework; DFT calculations and topological analysis of the electron density distribution within the framework of Bader?s theory (QTAIM method) confirmed these observations. Theoretical calculations showed that highly polarizable dichlorodiazadiene unit is capable of acting as a relatively strong halogen bond donor.

Авторы
Shikhaliyev N.G.1 , Maharramov A.M. 1 , Bagirova K.N.1 , Suleymanova G.T.1 , Tsyrenova B.D.2 , Nenajdenko V.G. 2 , Novikov A.S.3 , Khrustalev V.N. 4, 5 , Tskhovrebov A.G. 4, 6
Издательство
Royal Society of Chemistry
Номер выпуска
2
Язык
Английский
Страницы
191-193
Статус
Опубликовано
Том
31
Год
2021
Организации
  • 1 Baku State Univ, AZ-1148 Baku, Azerbaijan
  • 2 Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia
  • 3 St Petersburg State Univ, St Petersburg 199034, Russia
  • 4 Peoples Friendship Univ Russia, RUDN Univ, Moscow 117198, Russia
  • 5 Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia
  • 6 Russian Acad Sci, NN Semenov Fed Res Ctr Chem Phys, Moscow 119991, Russia
Ключевые слова
non-covalent interactions; crystal engineering; halogen bonding; azo dyes; DFT
Цитировать
Поделиться

Другие записи