The delta C-13, delta O-18 and Delta(47) records in biogenic, pedogenic and geogenic carbonate types from paleosol-loess sequence and their paleoenvironmental meaning

Paleoenvironmental reconstructions are commonly based on isotopic signatures of a variety of carbonate types, including rhizoliths and land-snail shells, present in paleosol-loess sequences. However, various carbonate types are formed through distinct biotic and abiotic processes over various periods, and therefore may record diverging environmental information in the same sedimentological layer. Here, we investigate the effects of carbonate type on delta C-13, delta O-18, and clumped isotope-derived paleotemperature [T(Delta(47))] from the Quaternary Nussloch paleosol-loess sequence (Rhine Valley, SW Germany). delta C-13, delta O-18, and T(Delta(47)) values of co-occurring rhizoliths (-8.2 parts per thousand to -5.8 parts per thousand, -6.1 parts per thousand to -5.9 parts per thousand, 12-32 degrees C, respectively), loess dolls (-7.0 parts per thousand, -5.6 parts per thousand, 23 degrees C), land-snail shells (-8.1 parts per thousand to -3.2 parts per thousand, -4.0 parts per thousand to -2.2 parts per thousand, 12-38 degrees C), earthworm biospheroliths (-11 parts per thousand, -4.7 parts per thousand, 8 degrees C), and "bulk" carbonates (-1.9 parts per thousand to -0.5 parts per thousand, -5.6 parts per thousand to -5.3 parts per thousand, 78-120 degrees C) from three sediment layers depend systematically on the carbonate type, admixture from geogenic carbonate, and the duration of formation periods. Based on these findings, we provide a comprehensive summary for the application of the three isotopic proxies of delta C-13, delta O-18, and Delta(47) in biogenic and pedogenic carbonates present in the same sediment layer to reconstruct paleoenvironments (e.g., local vegetation, evaporative conditions, and temperature). We conclude that bulk carbonates in Nussloch loess should be excluded from paleoenvironmental reconstructions. Instead, pedogenic and biogenic carbonates should be used to provide context for interpreting the isotopic signature for detailed site- and time-specific paleoenvironmental information.

Авторы
Zamanian K.1 , Lechler A.R.2 , Schauer A.J.3, 4 , Kuzyakov Y. 1, 5, 6 , Huntington K.W.3, 4
Журнал
Издательство
CAMBRIDGE UNIV PRESS
Язык
Английский
Страницы
256-272
Статус
Опубликовано
Номер
PII S003358942000109X
Том
101
Год
2021
Организации
  • 1 Univ Gottingen, Dept Soil Sci Temperate Ecosyst, Dept Agr Soil Sci, Busgenweg 2, D-37077 Gottingen, Germany
  • 2 Pacific Lutheran Univ, Dept Geosci, Tacoma, WA 98447 USA
  • 3 Univ Washington, Dept Earth & Space Sci, Seattle, WA 98195 USA
  • 4 Univ Washington, Quaternary Res Ctr, Seattle, WA 98195 USA
  • 5 Kazan Fed Univ, Inst Environm Sci, Kazan, Russia
  • 6 RUDN Univ, Agrotechnol Inst, Moscow 117198, Russia
Ключевые слова
Rhizoliths; Land-snail shells; Paleosol-loess sequence; Paleosol; Loess; Pedogenic carbonates; Clumped isotopes; Paleoenvironment reconstruction; CaCO3 formation
Дата создания
20.07.2021
Дата изменения
20.07.2021
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/74557/
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Другие записи

Bagdasaryan V.E., Bakaev A.A., Resnyansky S.I.
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