Cu(II) and Co(II) Complexes with (4Z)-4-[(2-Diethylaminoethylamino)methylene]-5-Methyl-2-Phenylpyrazol-3-one: Synthesis, Magnetic Properties, and Crystal Structures

Abstract: (4Z)-4-[(2-Diethylaminoethylamino)methylene]-5-methyl-2-phenylpyrazol-3-one (НL, product of the condensation of 5-hydroxy-3-methyl-1-phenylpyrazole-4-carbaldehyde with N,N-diethylethylenediamine) and its complexes CuL2 (I) and Co(L)CH3COO · CH3OH · H2O (II) are synthesized. The structures and compositions of the synthesized compounds are determined by elemental analysis, 1Н NMR and IR spectroscopy, and X-ray diffraction analysis (CIF files CCDC nos. 1971770 (I) and 1971772 (II)). Bis(chelate) pentacoordinated complex I has a distorted tetragonal pyramidal structure, and a distorted octahedral structure with the monodentate acetate anion and methanol and water molecules is observed for monochelate complex II. © 2020, Pleiades Publishing, Ltd.

Авторы
Burlov A.S. 1 , Vlasenko V.G. 2 , Lifintseva T.V.3 , Milutka M.S.1 , Koshchienko Y.V.1 , Uraev A.I.1 , Garnovskii D.A. 4 , Rusalev Y.V.5 , Lazarenko V.A. 6 , Khrustalev V.N. 7, 8
Журнал
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Номер выпуска
7
Язык
Английский
Страницы
485-492
Статус
Опубликовано
Ссылка
Внешняя ссылка
DOI
10.1134/S1070328420070015
Том
46
Год
2020
Организации
  • 1 Research Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
  • 2 Research Institute of Physics, Southern Federal University, Rostov-on-Don, Russian Federation
  • 3 Southern Federal University, Rostov-on-Don, Russian Federation
  • 4 Southern Scientific Center, Russian Academy of Sciences, Rostov-on-Don, Russian Federation
  • 5 The Smart Materials International Research Institute, Rostov-on-Don, Russian Federation
  • 6 Kurchatov Institute Russian Research Center, Moscow, 123182, Russian Federation
  • 7 Peoples Friendship University, Moscow, 117198, Russian Federation
  • 8 Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russian Federation
Ключевые слова
IR and 1Н NMR spectroscopy; magnetic properties; metal complexes; X-ray diffraction analysis
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