Hydrogen bonding in acetylene containing dichlorodiazaalkadienes

The detailed study of 1-aryl-4,4-dichloro-3-(2-propargyloxyphenyl)-1,2-diazabuta-1,3-dienes revealed the formation of dimeric structures via hydrogen bonding between the terminal acetylene hydrogen atom and the diazo fragment of the second molecule in the solid state, in solution the compounds being monomeric. This effect is confirmed by IR spectra, X-ray data as well as quantum chemical calculations. © 2020

Авторы
Tsyrenova B.D.1 , Tarasevich B.N.1 , Khrustalev V.N. 2, 3 , Gloriozov I.P.1 , Nenajdenko V.G. 1
Журнал
Mendeleev Communications
Издательство
Royal Society of Chemistry
Номер выпуска
5
Язык
Английский
Страницы
615-617
Статус
Опубликовано
Ссылка
Внешняя ссылка
DOI
10.1016/j.mencom.2020.09.021
Том
30
Год
2020
Организации
  • 1 Department of Chemistry, M. V. Lomonosov Moscow State University, Moscow, 119991, Russian Federation
  • 2 Peoples Friendship University of Russia (RUDN University), Moscow, 117198, Russian Federation
  • 3 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russian Federation
Ключевые слова
acetylene; alkynes; DFT calculation; diazadienes; H-bond; IR spectroscopy; structure; X-ray
Дата создания
02.11.2020
Дата изменения
02.11.2020
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/64425/
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