Synthesis, Structure and Magnetic Properties of Copper(II) Complexes of Diphenyl-(1-propylbenzimidazol-2-yl)methanol

Two types of binuclear copper complexes [LCuN3]2 and [LCuNO3]2.of bidentate ligand - diphenyl-(1-propylbenzimidazol-2-yl)methanol (HL) in the 4:1 ratio were synthesized. The crystal structure of copper complexes shows a centrosymmetric dimeric binuclear complex with two Cu2+ cations bridged by two oxygen atoms from two organic ligands. In the complexes, a very strong antiferromagnetic exchange interaction between copper atoms is observed. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Авторы
Burlov A.S. 1 , Koshchienko Y.V.1 , Vlasenko V.G. 2 , Bogomyakov A.S.3 , Kolodina A.A.1 , Zubavichus Y.V. 4 , Lazarenko V.A. 5 , Khrustalev V.N. 5, 6
Журнал
ChemistrySelect
Издательство
Wiley-Blackwell
Номер выпуска
29
Язык
Английский
Страницы
8652-8654
Статус
Опубликовано
Ссылка
Внешняя ссылка
DOI
10.1002/slct.201901186
Том
4
Год
2019
Организации
  • 1 Southern Federal University, Institute of Physical and Organic Chemistry, Stachki ave. 194/2 –, Rostov-on-Don, 344090, Russian Federation
  • 2 Southern Federal University, Institute of Physics, Stachki ave. 194 –, Rostov-on-Don, 344090, Russian Federation
  • 3 Siberian Branch of the Russian Academy of Sciences, International Tomography Center, Institutskaya St. 3a –, Novosibirsk -, 630090 –, Russian Federation
  • 4 Siberian Branch of the Russian Academy of Sciences, Boreskov Institute of Catalysis, Lavrentiev Ave. 5-, Novosibirsk -, 630090 –, Russian Federation
  • 5 National Research Center «Kurchatov Institute», Acad. Kurchatov Sq. 1–, Moscow -, 123182 –, Russian Federation
  • 6 Peoples' Friendship University of Russia (RUDN University), Miklukho-Maklaya ul. 6-, Moscow -, 117198 –, Russian Federation
Ключевые слова
antiferromagnetic exchange interaction; benzimidazole; binuclear copper complex; X-ray diffraction
Дата создания
24.12.2019
Дата изменения
24.12.2019
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/55564/
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