Cluster [Co3(CO)3(µ2-CO)3(µ3-C8H8)]– as a Ligand: Experimental and Theoretical Study

The cluster anion [Co3(CO)3(µ2-CO)3(µ3-C8H8)]– (2) reacts with fragments [(ring)M]+ and [(cod)M]+ to give the Co3M clusters (ring)MCo3(CO)3(µ3-CO)3(µ3-C8H8) {(ring)M = CpFe (3a), Cp*Fe (3b), CpRu (4a), (C4Me4)Co (5)} and (cod)MCo3(CO)3(µ3-CO)3(µ3-C8H8) {M = Rh (6), Ir (7)}, respectively. However, 2 does not form stable complexes with [(Ph3P)M]+ species (M = Cu, Ag, Au), which was explained on the basis of DFT calculations by the inefficient overlap between the cluster and fragment orbitals. The structures of 3b and 5 were determined by X-ray diffraction. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Авторы
Vinogradov M.M.1 , Perekalin D.S. 1 , Gutsul E.I.1 , Novikov V.V.1 , Smol'yakov A.F. 1, 2 , Wadepohl H.3 , Kudinov A.R.1 , Loginov D.A.1
Издательство
Wiley-VCH Verlag
Номер выпуска
48
Язык
Английский
Страницы
5663-5669
Статус
Опубликовано
Том
2017
Год
2017
Организации
  • 1 A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Science, 28 ul. Vavilova, Moscow, 119991, Russian Federation
  • 2 Faculty of Science, RUDN University, 6 Miklukho-Maklaya St., Moscow, 117198, Russian Federation
  • 3 Anorganisch-Chemisches Institut der Universität Heidelberg, Heidelberg, 69120, Germany
Ключевые слова
Anions; Clusters; Cobalt; Density functional theory calculations; Metal–metal interactions
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