1, 2, 5-Trimethyl-4-phenylethynylpiperidol-4 and its reactions

1, 2, 5-Trimethyl-4-phenylethynylpiperidol-4 and 1 2, 5-trirnethyl-4-ß-phenylethynylpiperidol-4 are prepared by various methods. Their interconversion is studied, and individual stereoisomeric forms of these piperidols isolated. 1, 2, 5-Trimethyl-4-phenylethynylpiperidol-4 is hydrated, and the resultant ω -(1,′ 2′, 5′-trimethyldidehydropiperidyl-4′) acetophenone used to effect synthesis of a number of secondary and tertiary carbinols. 2, 5-Dimethyl-4-ß-phenylethylpyridine is prepared from 1, 2, 5-trimethyl-4-ß-phenylethylpiperidol-4. © 1966 The Faraday Press, Inc.

Авторы
Издательство
Латвийский институт органического синтеза Латвийской академии наук / Springer New York Consultants Bureau
Номер выпуска
6
Язык
Английский
Страницы
576-581
Статус
Опубликовано
Том
1
Год
1966
Организации
  • 1 Patrice Lumumba Peoples' Friendship University, Moscow, Russian Federation
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Prostakov N.S., Mikheeva N.N., Phalgumani D., Mathew K.J.
Химия гетероциклических соединений. Латвийский институт органического синтеза Латвийской академии наук / Springer New York Consultants Bureau. Том 1. 1966. С. 355-358