Dissolution kinetics of nickel(II) and nickel(III) oxides in acid media

The rate of nickel(II) and nickel(III) oxide dissolution in sulfuric, hydrochloric, and nitric acids was measured as a function of the acid concentration and temperature, and a kinetic model of this process is suggested. The limiting step of the dissolution process is the passage of the complexes forming on the oxide surface into the solution.

Авторы
Pichugina N.M.1 , Kutepov A.M.2 , Gorichev I.G.3 , Izotov A.D.4 , Zaitsev B.E. 5
Номер выпуска
5
Язык
Английский
Страницы
485-494
Статус
Опубликовано
Том
36
Год
2002
Организации
  • 1 Moscow State Technical University, Bol'shaya Semenovskaya Ul. 38, Moscow, 105839 Russia, Russian Federation
  • 2 Moscow State Univ. of Environ. Eng., Staraya Basmannaya Ul. 21/4, Moscow, 107884 Russia, Russian Federation
  • 3 Moscow Pedagogical State University, Ul. kibal'chicha 6, Moscow, 129242 Russia, Russian Federation
  • 4 Kurnakov Inst. Gen. and Inorg. Chem., Russian Academy of Sciences, Leninskii Pr. 31, Moscow, 117907 R., Russian Federation
  • 5 Peoples Friendship University, Ul. Miklukho-Maklaya 6, Moscow, 117198 Russia, Russian Federation
Ключевые слова
hydrochloric acid; metal oxide; nickel; nitric acid; sulfuric acid; article; concentration (parameters); dissolution; kinetics; liquid culture; surface property; temperature
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/176/
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