A New Type of Phenanthrolinediamide Derivatives. Synthesis and Structure

Abstract: Starting from 5,6-dioxo-1,10-phenanthroline-2,9-dicarboxylic acid, the first examples of unsymmetrical 1,10-phenanthroline-2,9-diamides were obtained, simultaneously containing in their structure an oxo group in position 6 and a dichloromethylene fragment in position 5. The structure of the obtained compounds was confirmed by NMR spectroscopy and X-ray structural analysis. © Pleiades Publishing, Ltd. 2025.

Авторы
Lemport Pavel S. 1 , Sonin Igor V. 1 , Khrustalev Victor N. 2, 3 , Roznyatovsky V.A. 1 , Nenajdenko Valentine G. 1
Номер выпуска
6
Язык
Английский
Страницы
998-1003
Статус
Опубликовано
Том
61
Год
2025
Организации
  • 1 Faculty of Chemistry, Lomonosov Moscow State University, Moscow, Moscow Oblast, Russian Federation
  • 2 N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
  • 3 Department of Inorganic Chemistry, RUDN University, Moscow, Moscow Oblast, Russian Federation
Ключевые слова
functionalization; heterocycle; NMR; phenanthroline; X-ray
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