Crystal structure and Hirshfeld surface analysis of 4-methyl-N-[2-(5-methylfuran-2-yl)phenyl]-N-[(5-phenylfuran-2-yl)methyl]benzenesulfonamide

In the title compound, C29H25NO4S, the molecular conformation is stable with intramolecular C—H… … …O and C—H… … …N interactions being observed. In the crystal, molecules are linked by C—H… … …O interactions, forming layers parallel to the (100) plane. In addition, π–π [centroid-to-centroid distance = 3.4961 (7) Å] and C—H… … …π interactions connect the molecules within the layers. The layers are also bound to each other by van der Waals interactions. A Hirshfeld surface analysis of the crystal structure indicates that the most important contributions for the crystal packing are from H… … …H (53.2%), C… … …H/ H… … …C (28.9%) and O… … …H/H… … …O (13.8%) contacts. © 2025 International Union of Crystallography. All rights reserved.

Авторы
Annadurdyyeva Selbi 1 , Levina Anastasia E. 1 , Khrustalev Victor N. 1, 2 , Nazarova Roya Z. 3 , Hasanov Khudayar I. 4 , Sadikhova Nurlana D. 5 , Akkurt Mehmet 6 , Manahelohe Gizachew Mulugeta 7
Издательство
International Union of Crystallography
Номер выпуска
Pt 8
Язык
Английский
Страницы
706-710
Статус
Опубликовано
Том
81
Год
2025
Организации
  • 1 RUDN University, Moscow, Moscow Oblast, Russian Federation
  • 2 N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
  • 3 Baku Engineering University, Absheron, Azerbaijan
  • 4 Azerbaijan Medical University, Baku, Azerbaijan
  • 5 Department of Organic Chemistry, Baku State University, Baku, Azerbaijan
  • 6 Department of Physics, Erciyes Üniversitesi, Kayseri, Kayseri, Turkey
  • 7 Department of Chemistry, University of Gondar, Gondar, Amhara, Ethiopia
Ключевые слова
crystal structure; Hirshfeld surface analysis; hydrogen bond; van der Waals interactions
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