High-nuclearity Cu14 ionic complex featuring 1,3-bis(diphenylphosphino)propane and methylsilsesquioxane ligands: highly efficient catalysis of mild peroxidative alkane fuctionalizations

The first metallacomplex containing both 1,3-bis(diphenylphosphino)propane and silsesquoxane ligands is presented, which adopts an intriguing three-component ionic structure. According to X-ray diffraction studies, the central dianionic CuII12-methylsilsesquioxane cage is balanced by two external cationic [CuI (dppp)2] species, giving a total Cu14 nuclearity. The cage component of the complex encapsulates hydroxyl, carbonate, and chloride species. The complex was evaluated as a catalyst for the effective oxidation of alkanes to alkyl hydroperoxides and of alcohols to ketones using peroxides. This journal is © The Royal Society of Chemistry, 2026

Авторы
Arteev Ivan S. 1, 2, 3 , Khrustalev Victor N. 2, 3 , Shul’Pina Lidia S. 1 , Rodionov Alexey N. 1 , Shubina Elena S. 1 , Ragimov Karim G. 4 , Wang Zhi 5 , Bilyachenko Alexey N. 1
Журнал
Chemical Communications
Издательство
Royal Society of Chemistry
Номер выпуска
1
Язык
Английский
Страницы
181-184
Статус
Опубликовано
Ссылка
Внешняя ссылка
DOI
10.1039/D5CC05805H
Том
62
Год
2026
Организации
  • 1 A.N.Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
  • 2 RUDN University, Moscow, Moscow Oblast, Russian Federation
  • 3 N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
  • 4 Baku State University, Baku, Azerbaijan
  • 5 Key Laboratory of Colloid and Interface Chemistry, Shandong University, Jinan, Shandong, China
Ключевые слова
quinazolinone derivative; silsesquoxane; sodium siloxanolate; unclassified drug; alcohol; alcohol derivative; carbonic acid; cuprous ion; hydroperoxide; hydroxyl group; ketone; peroxide; Article; catalysis; catalytic efficiency; controlled study; deacetalization; energy transfer; fuctionalizations; hydrolysis; kaleidoscopy; kinetic parameters; nonhuman; oxidation; photophysics; structural diversity; structure analysis; three dimensional bioprinting; catalyst; female; ionization; Copper compounds; Dyes; Propane; X ray diffraction; Carbonates species; Catalyse; Cationics; Hydroxyl species; Ionic complex; Ionic structure; Methylsilsesquioxane; Nuclearity; Three-component; X-ray diffraction studies; Ligands; 1,3 bis(diphenylphosphino)propane; alkane; copper; copper ion; cyclohexanol; cyclohexanone derivative; hydrogen peroxide; lanthanide; ligand; metal ion; methylsilsesquioxane ligand; polymer
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