Crystal engineering of molecules with through-space α-effect hydrogen bonds: 3a,6 : 7,9a-diepoxybenzo[de]isoquinolines possessing a free amino group

The existence of a “through-space” alpha-effect is analyzed in all-cis 3a,6 : 4,5 : 7,9a-triepoxy and 3a,6 : 7,9a-diepoxybenzo[de]isoquinolines. It is demonstrated that the H-bonds are enhanced by the α-effect.

Авторы
Antonova A.S. 1 , Nikitina E.V. 1 , Valchuk K.S. 1 , Grigoriev M.S. 2 , Gomila R.M.3 , Frontera Antonio3 , Zubkov F.I. 1
Журнал
Издательство
Royal Society of Chemistry
Номер выпуска
34
Язык
Английский
Страницы
6093-6100
Статус
Опубликовано
Том
24
Год
2022
Организации
  • 1 A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky pr. 31, bld. 4, 119071 Moscow, Russian Federation
  • 2 Faculty of Science, Peoples' Friendship University of Russia (RUDN University), 6 Miklukho-Maklaya St, 117198 Moscow, Russian Federation
  • 3 Department of Chemistry, Universitat de les Illes Balears, Crta. de Valldemossa km 7.5, 07122 Palma de Mallorca (Baleares), Spain
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