Tuning Coordination in ZIF-67 Through the Solid-State Thermal Synthesis for Balancing Structural Stability and Catalytic Reactivity

Tailor-made unsaturated coordination of metal ions or organic linkers in zeolitic imidazole frameworks (ZIFs) has great potential in tuning the ZIFs’ properties and reactivity for their applications. Taking advantage of the solid-state thermal (SST) method as a facile and eco-friendly synthesis method, the rational coordination of metal ions with imidazole ligands in ZIF-67 through the SST method is investigated. The rational precursor ratio (metal-to-ligand source) under the solvent-free SST method emerges as a perfect strategy to tune the coordinately unsaturated sites within the ZIF-67 frameworks. Different analysis techniques, computational methods (DFT), and catalytic model reactions examine unsaturated coordination in ZIF-67 materials (defect structures). The unsaturated coordination provides unique characteristic properties on materials with excellent catalytic performance. However, the higher reactive properties are negotiated with weaker structural stability on materials. In addition, the post-SST approach is applied to enable rational coordination and modify the pristine ZIF-67 materials. The post-SST method rearranges and modifies coordination in the framework of materials. These findings are crucial to understanding the role of the uncoordinated degree to balance with structural stability based on ZIF-67, which is critical for effective heterogeneous catalysts. © 2024 American Chemical Society.