Synthesis and crystal structure of 7,7,10-trimethyl-7-silabenzo[a]anthrone

Skeletal isomerization of arylsilanes that occurs under conditions of catalytic dehydrocyclization and is accompanied by migration of the triorganosilyl group was additionally confirmed by dehydrocyclization of dimethyl(2,4-dimethylphenyl)(1-naphthyl)silane on chromium-containing oxide catalysts.

Authors
Polosin V.M.1 , Astakhov A.A.2 , Ryashentseva M.A.3 , Tafeenko V.A.4
Journal
Russian Chemical Bulletin
Number of issue
12
Language
English
Pages
2121-2123
Status
Published
Link
External link
DOI
10.1007/BF02495265
Volume
46
Year
1997
Organizations
  • 1 Stt. Sci. Res. Inst. Reagents E., 3 Bogorodsky val, 107076 Moscow, Russian Federation
  • 2 Russ. People's Frendship University, 6 ul. Miklukho-Maklaya, 117198 Moscow, Russian Federation
  • 3 N. D. Zelinsky Inst. of Organ. Chem., Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation
  • 4 Department of Chemistry, M. V. Lomonosov Moscow Stt. Univ., Vorob'evy Gory, 119899 Moscow, Russian Federation
Keywords
7,7,10-trimethyl-7-silabenzo[a]anthrone; Catalytic dehydrocyclization; X-ray structural analysis
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/779/
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