Acta Crystallographica Section E: Crystallographic Communications.
International Union of Crystallography.
Vol. 77.
2021.
3-Amino-1,2,4-triazolium salts as NHC-proligands: synthesis and postmodification of a new type of amino-functionalized Pd/NHC complexes
Palladium complexes with N-heterocyclic carbene ligands of a new type containing free NH2 group were obtained by direct palladation of 3-amino-1,4-dialkyl-1,2,4-triazolium salts. These amino-functionalized complexes were found to be a versatile platform for postmodification via reactions of the NH2 group with acyl and sulfonyl chlorides.
Authors
Pasyukov D.V.
1
,
Chernenko A.Y.1
,
Shepelenko K.E.1
,
Kutyrev V.V.1
,
Khrustalev V.N.
2,
3
,
Chernyshev V.M.
1
Journal
Publisher
Royal Society of Chemistry
Number of issue
2
Language
English
Pages
176-178
Status
Published
Volume
31
Year
2021
Organizations
- 1 Platov South Russian State Polytech Univ NPI, Novocherkassk 346428, Russia
- 2 Peoples Friendship Univ Russia, RUDN Univ, Moscow 117198, Russia
- 3 Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia
Keywords
3-amino-1,2,4-triazole; N-heterocyclic carbenes; palladium complexes; postmodification; catalysis
Date of creation
20.07.2021
Date of change
20.07.2021
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Other records
Mendeleev Communications.
Royal Society of Chemistry.
Vol. 31.
2021.
P. 191-193