Fullerenes Nanotubes and Carbon Nanostructures.
Taylor and Francis Inc..
2021.
Microwave-Assisted Cu(I)-Catalyzed Synthesis of Unsymmetrical 1,4-Diamino-2-butynes via Cross-A3-Coupling/Decarboxylative A3-Coupling
1,4-Diamino-2-butynes display both chemical and physiological properties. Here a highly efficient synthesis avenue to generate unsymmetric 1,4-diamino-2-butynes has been developed by microwave-assisted Cu(I)-catalyzed cross-A3-coupling/decarboxylative coupling of two different amines, formaldehyde, and propiolic acid through a domino process. This multicomponent reaction provides a series of target products in moderate to good yields with high chemoselectivity. © 2021 American Chemical Society.
Authors
Xu X.
1
,
Feng H.2
,
Van Der Eycken E.V.
Journal
Status
Published
Link
Year
2021
Organizations
- 1 Laboratory for Organic and Microwave-Assisted Chemistry (LOMAC), Department of Chemistry, Ku Leuven, Celestijnenlaan 200F, Leuven, 3001, Belgium
- 2 College of Chemistry and Chemical Engineering, Shanghai Engineering Research Center of Textile Chemistry and Cleaner Production, Shanghai University of Engineering Science, Shanghai, 201620, China
- 3 Peoples' Friendship University of Russia (RUDN University), 6 Miklukho-Maklaya Street, Moscow, 117198, Russian Federation
Date of creation
20.07.2021
Date of change
20.07.2021
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