International Journal on Minority and Group Rights. Том 10. 2003. С. 203-220
Intramolecular nucleophilic addition of carbanions generated from: N -benzylamides to cyclopropenes
An unusual reaction is described, involving a formal intramolecular nucleophilic substitution of bromocyclopropanes with nitrogen ylides generated in situ from N-benzyl carboxamides. It is shown that this reaction involves cyclopropene intermediates and allows for the facile and expeditious preparation of 3-azabicyclo[3.1.0]hexan-2-one scaffolds. © 2017 The Royal Society of Chemistry.
Авторы
Maslivetc V. 1 , Barrett C. 1 , Aksenov N.A. 2 , Rubina M. 1, 3 , Rubin M. 1, 2
Издательство
Royal Society of Chemistry
Номер выпуска
2
Язык
English
Страницы
285-294
Статус
Published
Ссылка
Том
16
Год
2018
Организации
- 1 Department of Chemistry, University of Kansas, 1251 Wescoe Hall Dr., Lawrence, KS 66045-7582, United States
- 2 Department of Chemistry, North Caucasus Federal University, 1a Pushkin St., Stavropol, 355009, Russian Federation
- 3 Peoples Friendship University of Russia, 6 Miklukho-Maklaya st., Moscow, 117198, Russian Federation
Ключевые слова
Addition reactions; Scaffolds; Carboxamides; Cyclopropenes; Nucleophilic additions; Nucleophilic substitutions; Reaction intermediates
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