Crystal Structure of Tris- (2,3,5,6-Tetrafluorobenzoato)Scandium [Sc(C6F4HCO2)3]

The heating of a mixture of as-precipitated scandium hydroxide and tetrafluoroterephthalic acid in methanol is accompanied by acid decarboxylation and the formation of a tris-(2,3,5,6- tetrafluorobenzoato)scandium complex compound. According to the data of the single crystal X-ray diffraction analysis, the compound has a chain structure due to the carboxylate anion functioning as a μ2-bridging ligand. The polymer chains are linked together by interactions between the phenyl rings. © 2018, Pleiades Publishing, Ltd.

Authors
Cheplakova A.M.1, 2 , Fedoseev I.S.2 , Dorovatovskii P.V.3 , Lazarenko V.A.3 , Zubavichus Y.V.3 , Khrustalev V.N. 4 , Fedin V.P.1, 2
Journal
Journal of Structural Chemistry
Number of issue
2
Language
English
Pages
494-496
Status
Published
Link
External link
DOI
10.1134/S0022476618020348
Volume
59
Year
2018
Organizations
  • 1 Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russian Federation
  • 2 Novosibirsk State University, Novosibirsk, Russian Federation
  • 3 National Research Center “Kurchatov Institute”, Moscow, Russian Federation
  • 4 Peoples’ Friendship University of Russia, Moscow, Russian Federation
Keywords
coordination polymer; crystal structure; scandium complexes; tetrafluorobenzoic acid; tetrafluoroterephthalic acid
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/6820/
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