Specific Features of the Molecular Structure of A New 3-(Benzo[d]Oxazole-2-Yl)- 1-(2-(1,3,3-Trimethylindoline-2-Ylidene) Ethylidene)Naphthalene-2(1H)-One Zinc Chloride Complex

X-ray diffraction is used to determine the structure of a new 3-(benzo[d]oxazole-2-yl)-1-(2-(1,3,3- trimethylindoline-2-ylidene)ethylidene)naphthalene-2(1H)-one zinc chloride complex 1. It is demonstrated that the ligand molecule in complex 1 has a trans–trans–cis conformation in which the indoline nitrogen atom is oriented in the same direction as the chelate ring, which could promote an additional coordination with the complexing atom. © 2018, Pleiades Publishing, Ltd.

Authors
Tkachev V.V.1 , Utenyshev A.N.1, 4 , Chernyshov A.I.2 , Kovalchukova O.V. 3
Journal
Journal of Structural Chemistry
Number of issue
2
Language
English
Pages
425-428
Status
Published
Link
External link
DOI
10.1134/S0022476618020245
Volume
59
Year
2018
Organizations
  • 1 Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
  • 2 Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
  • 3 Peoples’ Friendship University of Russia, Moscow, Russian Federation
  • 4 Sechenov First Moscow State Medical University of the Ministry of Health of the Russian Federation, Moscow, Russian Federation
Keywords
3-(benzo[d]oxazole-2-yl)-1-(2-(1,3,3-trimethylindoline-2-ylidene)ethylidene)naphthalene-2(1H)-one zinc chloride; spiropyrans; X-ray diffraction study
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/6818/
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