Efficient mechanochemical bifunctional nanocatalysts for the conversion of isoeugenol to vanillin

A bifunctional nanocatalyst composed of iron containing SBA-15 material modified with sulfonic acid groups was synthesized by a mechanochemical approach. A full characterization of the obtained nanocatalyst was performed by N2 physisorption isotherms analysis, transmission electron microscopy (TEM), X-ray powder diffraction (XRD) and Fourier-Infrared Spectroscopy (FT-IR). The mechanochemically synthesized nanocatalyst displays a high isoeugenol conversion to vanillin under mild conditions using H2O2 as oxidizing agent. Interestingly, this conversion resulted to be higher than that one obtained with the same material synthesized by an impregnation method. Additionally, the nanocatalyst showed excellent reusability over four successive runs under the studied reaction conditions. © 2018 Ostovar, Franco, Puente-Santiago, Pinilla-de Dios, Rodríguez-Padrón, Shaterian and Luque.

Authors

Ostovar S.^1, ² , Franco A.² , Puente-Santiago A.R.² , Pinilla-de Dios M. , Rodríguez-Padrón D.² , Shaterian H.R.¹ , Luque R. ^2, ³

Journal

Frontiers in Chemistry

Publisher

Frontiers Media S. A

Number of issue

APR

Language

English

Status

Published

Link

External link

DOI

10.3389/FCHEM.2018.00077

Number

Volume

Year

2018

Organizations

¹ Department of Chemistry, University of Sistan and Baluchestan, Zahedan, Iran
² Grupo FQM-383, Departamento de Química Orgánica, Universidad de Cordoba, Cordoba, Spain
³ Peoples Friendship University of Russia, Moscow, Russian Federation

Keywords

Catalytic oxidation; Nanocatalyst; SBA-15; Sulfonic groups; vanillin

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ГОСТ MLA RIS BibTex

INDUCTION OF APOPTOTIC ENDONUCLEASE ENDOG WITH DNA-DAMAGING AGENTS INITIATES ALTERNATIVE SPLICING OF TELOMERASE CATALYTIC SUBUNIT HTERT AND INHIBITION OF TELOMERASE ACTIVITY HTERT IN HUMAN CD4+ AND CD8+ Т LYMPHOCYTES

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Zhdanov D.D., Vasina D.A., Orlova V.S., Orlova E.V., Grishin D.V., Gladilina Y.A., Pokrovskaya M.V., Aleksandrova S.S., Sokolov N.N.

Biochemistry (Moscow) Supplement Series B: Biomedical Chemistry. Vol. 12. 2018. P. 119-129

SYNTHESIS, CRYSTAL STRUCTURE AND CATALYTIC ACTIVITY IN REDUCTIVE AMINATION OF DICHLORIDO(Η6 - P -CYMENE)(2′-DICYCLOHEXYLPHOSPHANYL-2,6-DIMETHOXYBIPHENYL-Κ P)RUTHENIUM(II)

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Makarova M., Tsygankov A.A., Chusova O., Linko I.V., Dorovatovskii P.V., Zubavichus Y.V.

Acta Crystallographica Section E: Crystallographic Communications. International Union of Crystallography. Vol. 74. 2018. P. 487-491

Efficient mechanochemical bifunctional nanocatalysts for the conversion of isoeugenol to vanillin

Other records

INDUCTION OF APOPTOTIC ENDONUCLEASE ENDOG WITH DNA-DAMAGING AGENTS INITIATES ALTERNATIVE SPLICING OF TELOMERASE CATALYTIC SUBUNIT HTERT AND INHIBITION OF TELOMERASE ACTIVITY HTERT IN HUMAN CD4+ AND CD8+ Т LYMPHOCYTES

SYNTHESIS, CRYSTAL STRUCTURE AND CATALYTIC ACTIVITY IN REDUCTIVE AMINATION OF DICHLORIDO(Η6 - P -CYMENE)(2′-DICYCLOHEXYLPHOSPHANYL-2,6-DIMETHOXYBIPHENYL-Κ P)RUTHENIUM(II)

Cite