International Journal of Geometric Methods in Modern Physics.
Vol. 15.
2018.
CF3-Carbenoid functionalization of N-(pyrimidin-2-yl)indole catalyzed by cobalt complexes: Ligand control of selectivity
The carbonyl cobalt complex Cp*Co(CO)I2 catalyzes carbenoid Co alkylation of N-(pyrimidin-2-yl)indole with methyl 3,3,3-trifluoro-2-diazopropionate regioselectively giving 2-substituted indole, while the N,N’-ligated cations [CpCo(L)I]+ (L = bipy, phen) provide 3-substitution exclusively. The structure of [CpCo(phen)I]PF6 was investigated by X-ray diffraction.[Figure presented] © 2018
Authors
Kuvshinova S.S.1
,
Smol'yakov A.F.
1,
2
,
Vorobyeva D.V.1
,
Osipov S.N.1
,
Loginov D.A.1
Journal
Publisher
Royal Society of Chemistry
Number of issue
4
Language
English
Pages
359-361
Status
Published
Link
Volume
28
Year
2018
Organizations
- 1 A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 119991, Russian Federation
- 2 Peoples Friendship University of Russia (RUDN University), Moscow, 117198, Russian Federation
Share
Other records
Biomedical Engineering.
Springer New York LLC.
Vol. 52.
2018.
P. 84-86