Peculiarities of Dehydrogenation and Destruction of Propane in Transitional Catalytic Systems MeVOx (Me = La, Sm, Er)

Abstract: Features of propane conversion in the presence of rare-earth metal vanadite and vanadate, both produced via solid-phase synthesis, are studied. It is shown that MeVO3 catalyzes mainly the propane cracking process to form methane and ethylene, while MeVO4 equally accelerates both cracking and dehydrogenation of propane. The thermal stability of MeVO4 in a hydrogen atmosphere is studied by a temperature-programmed reduction, while the MeVO3 stability in an oxidizing environment is studied by DTA. Energies of activation for the MeVO3 reduction and the MeVO4 oxidation are calculated using the Kissinger method. © 2020, King Fahd University of Petroleum & Minerals.

Authors
Markova E.B. 1 , Kurilkin V.V. 1 , Safir R.E. 1 , Cherednichenko A.G. 1 , Sheshko T.F. 1 , Khozina E.V.2
Journal
Arabian Journal for Science and Engineering
Publisher
Springer Verlag
Language
English
Status
Published
Link
External link
DOI
10.1007/s13369-020-04589-1
Year
2020
Organizations
  • 1 RUDN University (Peoples’ Friendship University of Russia), Moscow, 117198, Russian Federation
  • 2 Frumkin Institute of Physical Chemistry and Electrochemistry RAS Leninskiy Prospect, 31, Moscow, 119071, Russian Federation
Keywords
DTA; Kissinger method; Propane cracking; Propane dehydrogenation; Vanadate; Vanadite
Date of creation
02.11.2020
Date of change
02.11.2020
Short link
https://repository.rudn.ru/en/records/article/record/65402/
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