Batch versus Continuous Flow Performance of Supported Mono- and Bimetallic Nickel Catalysts for Catalytic Transfer Hydrogenation of Furfural in Isopropanol

Furfural takes an important position in hemicelluloses biorefinery platforms. It can be converted into a wide range of chemicals. One important valorization route is the catalytic hydrogenation. Whereas molecular hydrogen is mostly used in industrial hydrogenation processes, recent studies also showed that alcohols can be used as reductants from which hydrides can be transferred catalytically to furfural. This process is often assisted by the formation of significant amounts of side products, in despite of high yields to the hydrogenolysis product 2-methylfuran. The present work explores the catalytic behavior in batch and continuous flow of mono- and bimetallic nickel catalysts supported on activated carbon for the catalytic transfer hydrogenation of furfural in isopropanol. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim