Human Physiology.
Vol. 46.
2020.
P. 540-547
Hydrogenation of plant polyalkoxybenzene derivatives: convenient access to coenzyme Q0 analogues
A technologically advanced protocol has been developed for converting plant allyl(polyalkoxy)benzenes to methyl- and propyl(polyalkoxy)benzenes being intermediates in the syntheses of coenzyme Q0 analogues. The key stage of allyl and benzaldehyde moieties hydrogenation was carried out in a periodical autoclave mode on highly porous ceramic block Pd-catalysts. These catalysts possess large surface area, low hydraulic resistance, significant thermal and mechanical stabililty, multiple cycling and easy regeneration, which can dramatically reduce Pd consumption. © 2020
Authors
Varakutin A.E.1
,
Muravsky E.A.2
,
Shinkarev I.Y.2
,
Khrustalev V.N.
1,
3
,
Semenov V.V.
1
Journal
Publisher
Royal Society of Chemistry
Number of issue
5
Language
English
Pages
599-601
Status
Published
Link
Volume
30
Year
2020
Organizations
- 1 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russian Federation
- 2 D. I. Mendeleev University of Chemical Technology of Russia, Moscow, 125047, Russian Federation
- 3 Peoples Friendship University of Russia (RUDN University), Moscow, 117198, Russian Federation
Keywords
alkyl(polyalkoxy)benzenes; antioxidants; ceramic block catalysts; coenzyme Q0; hydrogenation; palladium catalysts
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Other records
Mendeleev Communications.
Royal Society of Chemistry.
Vol. 30.
2020.
P. 615-617