Reductive amination catalyzed by iridium complexes using carbon monoxide as a reducing agent

Development of novel, sustainable catalytic methodologies to provide access to amines represents a goal of fundamental importance. Herein we describe a systematic study for the construction of a variety of amines catalyzed by a well-defined homogeneous iridium complex using carbon monoxide as a reducing agent. The methodology was shown to be compatible with functional groups prone to reduction by hydrogen or complex hydrides. © The Royal Society of Chemistry 2017.

Authors
Moskovets A.P.1 , Usanov D.L.2 , Afanasyev O.I.1 , Fastovskiy V.A.1 , Molotkov A.P.1 , Muratov K.M.1 , Denisov G.L.1 , Zlotskii S.S.3 , Smol'Yakov A.F. 1, 4 , Loginov D.A.1 , Chusov D. 1, 4
Journal
Organic and Biomolecular Chemistry
Publisher
Royal Society of Chemistry
Number of issue
30
Language
English
Pages
6384-6387
Status
Published
Link
External link
DOI
10.1039/c7ob01005b
Volume
15
Year
2017
Organizations
  • 1 A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova St. 28, Moscow, 119991, Russian Federation
  • 2 Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, MA 02138, United States
  • 3 Ufa Oil Institute, Kosmonavtov Str. 1, Ufa, 450062, Russian Federation
  • 4 Faculty of Science, RUDN University, 6 Miklukho-Maklaya St., Moscow, 117198, Russian Federation
Keywords
Amines; Carbon monoxide; Catalysis; Iridium; Complex hydrides; Iridium complex; Reduction by hydrogens; Reductive amination; Systematic study; Iridium compounds
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/6299/
Share

Other records