Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya.
Vol. 45.
2019.
P. 512-516
Salt Na2[OsCl6] is obtained by the interaction of H2[OsCl6]·H2O with NaCl in boiling concentrated hydrochloric acid. According to the single crystal X-ray diffraction data, the substance crystallizes in the cubic system, space group Fm3̄m, a = 9.7461(11) Å, V= 925.8(3) Å3, Z = 4, R1= 0.029, wR2 = 0.070. The compound is characterized by UV-vis and IR spectroscopy.